a/ \(2CO\left(0,2\right)+O_2\left(0,1\right)\rightarrow2CO_2\left(0,2\right)\)

\(2H_2\left(0,1\right)+O_2\left(0,05\right)\rightarrow2H_2O\left(0,1\right)\)

\(n_{H_2O}=\frac{1,8}{18}=0,1\)

\(n_{O_2}=\frac{3,36}{22,4}=0,15\)

Số mol O₂ phản ứng ở phản ứng đầu là: \(0,15-0,05=0,1\)

\(\Rightarrow m_{CO_2}=0,2.44=8,8\)

b/ \(m_{CO}=0,2.28=5,6\)

\(m_{H_2}=0,1.2=0,2\)

c/ \(\%CO=\frac{0,2}{0,3}.100\%=66,67\%\)

\(\Rightarrow\%H_2=100\%-66,67\%=33,33\%\)

\(a)\\ 2CO + O_2 \xrightarrow{t^o} 2CO\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{H_2} = n_{H_2O} = \dfrac{1,8}{18} = 0,1(mol)\\ \)

Theo PTHH :

\(2n_{O_2} = n_{CO} + n_{H_2}\\ \Leftrightarrow 2.\dfrac{3,36}{22,4} = n_{CO} + 0,1\\ \Leftrightarrow n_{CO} = 0,2(mol)\\ \%V_{H_2} = \dfrac{0,1}{0,1+ 0,2}.100\% = 33,33\%\\ \%V_{CO} = 100\%-33,33\% = 66,67\%\\ c) Cách\ 1 :\\ n_{CO_2} = n_{CO} = 0,2(mol)\\ m_{CO_2} = 0,2.44 = 8,8(gam)\\ Cách\ 2 : \\ m_{hh} = m_{CO} + m_{H_2} = 0,2.28 + 0,1.2 = 5,8(gam) \)

Bảo toàn khối lượng :

\(m_{hh} + m_{O_2} = m_{H_2O} + m_{CO_2}\\ \Rightarrow m_{CO_2} = 5,8 + 0,15.32 - 1,8 = 8,8(gam)\)

a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\)  (1)

                \(4H_2+O_2\underrightarrow{t^o}2H_2O\)  (2)

b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)

c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)

Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)

\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)

a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)

\(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,25\left(mol\right)\\n_{C_2H_2}=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,25.22,4}{6,72}.100\%\approx83,33\%\\\%V_{C_2H_2}\approx16,67\%\end{matrix}\right.\)

Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=0,625\left(mol\right)\Rightarrow m_{O_2}=0,625.32=20\left(g\right)\)

\(2CO + O_2 \xrightarrow{t^o} 2CO_2\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{CO} = n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{n_{CO} + n_{H_2}}{2}=\dfrac{0,2+n_{H_2}}{2} = \dfrac{9,6}{32} = 0,3(mol)\\ \Rightarrow n_{H_2} = 0,4(mol)\\ \%V_{CO} = \dfrac{0,2}{0,2 + 0,4}.100\% = 33,33\%\\ \%V_{H_2} = 100\% - 33,33\% = 66,67\%\\ \%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\%=87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)

Bài 2.

\(n_{C_2H_2}=\dfrac{4,48}{22,4}=0,2mol\)

\(n_{O_2}=\dfrac{6,72}{22,4}=0,3mol\)

\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)

0,2    >      0,3                                             ( mol )

                  0,3             0,24       0,12           ( mol )

\(m_{CO_2}=0,24.44=10,56g\)

\(m_{H_2O}=0,12.18=2,16g\)

PTHH: 2CO + O2→2CO2

C2H4 + 3O2→ 2CO2 +2 H2O

nH2O= mM=\(\dfrac{1,8}{18}\)=0,1(mol)

nC2H4=\(\dfrac{1}{2}\).nH2O=\(\dfrac{1}{2}\).0,1=0,05(mol)

=> VC2H4=n.22,4=0,05.22,4=1,12(lít)

->VCO=4,48 − 1,12= 3,36(lít)

b)  nCO2 (1)=nCO=\(\dfrac{3,36}{22,4}\)=0,15(mol)

mCO2 (1)=n.M=0,15.44=6,6(g)

nCO2 (2)=2.nC2H4=2.0,05=0,1(mol)

mCO2 (2)=n.M=0,1.44=4,4(g)

mCO2 sau pư=6,6 + 4,4= 11(g)